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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/100/3027

Title: Transition metal catalyzed [2+2+2] cycloaddition and application in organic synthesis
Authors: KOTHA, S
BRAHMACHARY, E
LAHIRI, K
Keywords: cyclotrimerization
heterocycles
polycycles
strained molecules
transition metals
Issue Date: 2005
Publisher: WILEY-V C H VERLAG GMBH
Citation: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,(22)4741-4767
Abstract: The [2+2+2] cycloaddition strategy is complementary to the well known Diels-Alder reaction for the generation of polycyclic compounds. This [2+2+2] approach is atom-economical and, with the availability of new catalysts to effect the [2+2+2] cycloaddition reaction, synthesis of a wide variety of highly functionalized polycycles is possible. This review deals with some recent advances relating to [2+2+2] cycloaddition reactions involving the syntheses both of polycycles and of heterocycles. More specifically, syntheses of various biologically active molecules, unusual amino acids, and theoretically interesting molecules are described. An attempt has also been made to give an overview of recent advances in the achievement of chemo-, regio-, and stereoselectivity in cyclotrimerization reactions. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
URI: http://dx.doi.org/10.1002/ejoc.200500411
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13789
http://hdl.handle.net/100/3027
ISSN: 1434-193X
Appears in Collections:Review

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