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|Title:||Anhydrous manganese hypophosphite dense framework solid: Synthesis, structure and magnetic studies|
|Keywords:||Metal Formate Framework|
|Publisher:||ELSEVIER SCIENCE BV|
|Citation:||INORGANIC CHEMISTRY COMMUNICATIONS, 59,84-87|
|Abstract:||Anhydrous manganese hypophosphite, [Mn(H2PO2)(2)](n)center dot(DMF)(0.11) (I) has been isolated under solvothermal conditions from the reaction of hypophosphorous acid (H3PO2) and MnCl2 center dot 4H(2)O in a mixture of DMF/EtOH/H2O (8:1:1; v/v) in 60% yield. The compound is characterized by FT-IR spectroscopy, thermogravimetric analysis, PXRD, single crystal X-ray diffraction data and magnetic measurements. The ligand occupies all the octahedral coordination sites around Mn(II) ions and forms a dense 3-D coordination polymer with hexagonal 1-0 channels along  direction. The Mn(II) ions in the framework exhibit weak antiferromagnetic interactions. (C) 2015 Elsevier B.V. All rights reserved.|
|Appears in Collections:||Article|
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