Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/100/15746
Title: Development of the First Menthane-Based Chiral Bis(p-allylpalladium) Catalysis: Asymmetric Allylation of Imines
Authors: FERNANDES, RA
CHAUDHARI, DA
Keywords: Asymmetric Catalysis
Homogeneous Catalysis
C-C Coupling
Allyl-Ation
Palladium
Enantioselectivity
Issue Date: 2012
Publisher: WILEY-V C H VERLAG GMBH
Citation: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (10)1945-1952
Abstract: A new ethylidene menthane-based chiral p-allylpalladium complex catalyzes the asymmetric allylation of various imines with allyltributylstannane and 1 equiv. of water to give chiral homoallylamines in good yields and enantioselectivities. The reaction was carried out essentially under neutral conditions and displayed a good transfer of chiral information from the menthane skeleton through the formation of a bis(p-allylpalladium) species. This is the first example of menthane-based chiral bis(p-allylpalladium) catalysis.
URI: http://dx.doi.org/10.1002/ejoc.201101588
http://dspace.library.iitb.ac.in/jspui/handle/100/15746
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