Please use this identifier to cite or link to this item:
|Title:||Development of the First Menthane-Based Chiral Bis(p-allylpalladium) Catalysis: Asymmetric Allylation of Imines|
|Publisher:||WILEY-V C H VERLAG GMBH|
|Citation:||EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (10)1945-1952|
|Abstract:||A new ethylidene menthane-based chiral p-allylpalladium complex catalyzes the asymmetric allylation of various imines with allyltributylstannane and 1 equiv. of water to give chiral homoallylamines in good yields and enantioselectivities. The reaction was carried out essentially under neutral conditions and displayed a good transfer of chiral information from the menthane skeleton through the formation of a bis(p-allylpalladium) species. This is the first example of menthane-based chiral bis(p-allylpalladium) catalysis.|
|Appears in Collections:||Article|
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.