Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/100/15207
Title: Synthesis, structure and redox property of first 1,2,3-triselenole
Authors: MATHUR, P
RAI, DK
TAUQEER, M
JOSHI, RK
LAHIRI, GK
MOBIN, SM
Keywords: Chalcogenole
Triselenole
Demetallation
Cyclic Voltammetry
Issue Date: 2012
Publisher: ELSEVIER SCIENCE SA
Citation: JOURNAL OF ORGANOMETALLIC CHEMISTRY, 721144-147
Abstract: Photolysis of [Fe3Se2(CO)(9)] with 3-ferrocenylpropynal in hexane yields an adduct of [Fe2Se2(CO)(6)] and FcC(2)CHO, [(CO)(6)Fe-2{mu-SeC(Fc)]=C(CHO)Se}] (1). Subsequent reaction of 1 with [Fe2Se2(CO)(6)] in presence of excess of Me3NO center dot 2H(2)O in THF leads to formation of a novel 5-ferrocenyl-4-carbaldehyde-1,2,3-triselenole (2). Its electrochemistry has been investigated by cyclic voltammetry, which shows two successive quasi-reversible oxidations. (C) 2012 Elsevier B. V. All rights reserved.
URI: http://dx.doi.org/10.1016/j.jorganchem.2012.09.009
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