Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/100/14869
Title: Detecting Bifurcations in an Electrochemical Cell Employing an Assisted Reference Model Strategy
Authors: RAMIREZ-ALVAREZ, E
RAMIREZ, MC
RICO-MARTINEZ, R
GONZALEZ-FIGUEREDO, C
PARMANANDA, P
Issue Date: 2013
Publisher: AMER CHEMICAL SOC
Citation: JOURNAL OF PHYSICAL CHEMISTRY A, 117(3)535-540
Abstract: Bifurcations are detected in experiments involving the electrochemical oxidation of copper in phosphoric acid. Ideally, a bifurcation detection protocol requires a model with good qualitative and quantitative prediction capabilities that is also able to reproduce the drift inherent to the electrochemical experiment. A generic protocol for manipulation of nonlinear systems is proposed to achieve this goal. This protocol is based on a good qualitative predictor coupled to a modified Kalman filter that corrects the quantitative errors of the model point by point, adapting to the slowly varying conditions imposed by the electrochemical drift.
URI: http://dx.doi.org/10.1021/jp310127a
http://dspace.library.iitb.ac.in/jspui/handle/100/14869
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