DSpace at IIT Bombay >
IITB Publications >
Please use this identifier to cite or link to this item:
|Title: ||Reductive Studies on 3-Oxidopyrylium-alkene [5+2] Cycloadducts: Access to Some Hydroxy Cycloheptenoids|
|Authors: ||YADAV, AA|
|Keywords: ||SYNTHETICALLY USEFUL REACTIONS|
|Issue Date: ||2011|
|Publisher: ||TAYLOR & FRANCIS INC|
|Citation: ||SYNTHETIC COMMUNICATIONS,41(9)1326-1337|
|Abstract: ||[image omitted] The scope of nickel boride as a versatile reducing reagent is extended to the 3-oxidopyrylium-alkene [5+2] cycloadducts. In this report, we demonstrate that nickel boride is capable of one-pot 1,2- and 1,4-reduction of enones present in the cycloadducts in good yields. Subsequent elaboration of the cycloadducts towards synthesis of functionalized cycloheptenoid derivatives devoid of the oxa-bridge is also explored.|
|Appears in Collections:||Article|
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.