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|Title:||Reductive Studies on 3-Oxidopyrylium-alkene [5+2] Cycloadducts: Access to Some Hydroxy Cycloheptenoids|
|Keywords:||Synthetically Useful Reactions|
|Publisher:||TAYLOR & FRANCIS INC|
|Abstract:||[image omitted] The scope of nickel boride as a versatile reducing reagent is extended to the 3-oxidopyrylium-alkene [5+2] cycloadducts. In this report, we demonstrate that nickel boride is capable of one-pot 1,2- and 1,4-reduction of enones present in the cycloadducts in good yields. Subsequent elaboration of the cycloadducts towards synthesis of functionalized cycloheptenoid derivatives devoid of the oxa-bridge is also explored.|
|Appears in Collections:||Article|
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