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|Title: ||Role of the conformational changes brought in the arms of the 1,3-di-capped conjugate of calixarene (L) in turning on the fluorescence of L by Hg(2+)|
|Authors: ||BANDELA, A|
|Keywords: ||SELECTIVE RECOGNITION|
|Issue Date: ||2011|
|Publisher: ||ROYAL SOC CHEMISTRY|
|Citation: ||DALTON TRANSACTIONS,40(43)11367-11370|
|Abstract: ||A new 1,3-di-capped calixarene conjugate of salicylidene (L) has been synthesized, characterized and the structure has been established by single crystal XRD. L shows selectivity towards Hg(2+) in ethanol by turn-on fluorescence among the biologically important metal ions studied. The species of recognition has been modeled by DFT computational calculations to result in conformational changes in the arms that support the turn-on fluorescence behaviour.|
|Appears in Collections:||Article|
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