New hexaphosphane ligands 1,3,5-C(6)H(3){p-C(6)H(4)N(PX(2))(2)}(3) [ X = Cl, F, C(6)H(3)OMe(C(3)H(5))]: Synthesis, derivatization and palladium(II) and platinum(II) complexes

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Title:	New hexaphosphane ligands 1,3,5-C(6)H(3){p-C(6)H(4)N(PX(2))(2)}(3) [ X = Cl, F, C(6)H(3)OMe(C(3)H(5))]: Synthesis, derivatization and palladium(II) and platinum(II) complexes
Authors:	RAO, S GANESAMOORTHY, C MOBIN, SM BALAKRISHNA, MS
Keywords:	METAL-ORGANIC FRAMEWORKS BIMETALLIC HYDROFORMYLATION COORDINATION CHEMISTRY HIGH REGIOSELECTIVITY HYDROGEN STORAGE PHENYLENE-1,4-DIAMINOTETRA(PHOSPHONITE) COOPERATIVITY ADSORPTION
Issue Date:	2011
Publisher:	ROYAL SOC CHEMISTRY
Citation:	DALTON TRANSACTIONS,40(22)5841-5843
Abstract:	A novel dodecachlorohexaphosphane, 1,3,5-C(6)H(3)[p-C(6)H(4)N(PCl(2))(2)](3) (1) was synthesized by reacting 1,3,5-tris(4'-anilino) benzene with phosphorus trichloride. Fluorination of 1 with SbF(3) produces 1,3,5-C(6)H(3)[p-C(6)H(4)N(PF(2))(2)](3) (2). The derivatization of chlorohexaphosphane with an aryloxy substituent and its palladium(II) and platinum(II) complexes are also described.
URI:	http://dx.doi.org/10.1039/c1dt10459d http://dspace.library.iitb.ac.in/jspui/handle/100/14287
ISSN:	1477-9226
Appears in Collections:	Article

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