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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/100/14287

Title: New hexaphosphane ligands 1,3,5-C(6)H(3){p-C(6)H(4)N(PX(2))(2)}(3) [ X = Cl, F, C(6)H(3)OMe(C(3)H(5))]: Synthesis, derivatization and palladium(II) and platinum(II) complexes
Authors: RAO, S
GANESAMOORTHY, C
MOBIN, SM
BALAKRISHNA, MS
Keywords: METAL-ORGANIC FRAMEWORKS
BIMETALLIC HYDROFORMYLATION
COORDINATION CHEMISTRY
HIGH REGIOSELECTIVITY
HYDROGEN STORAGE
PHENYLENE-1,4-DIAMINOTETRA(PHOSPHONITE)
COOPERATIVITY
ADSORPTION
Issue Date: 2011
Publisher: ROYAL SOC CHEMISTRY
Citation: DALTON TRANSACTIONS,40(22)5841-5843
Abstract: A novel dodecachlorohexaphosphane, 1,3,5-C(6)H(3)[p-C(6)H(4)N(PCl(2))(2)](3) (1) was synthesized by reacting 1,3,5-tris(4'-anilino) benzene with phosphorus trichloride. Fluorination of 1 with SbF(3) produces 1,3,5-C(6)H(3)[p-C(6)H(4)N(PF(2))(2)](3) (2). The derivatization of chlorohexaphosphane with an aryloxy substituent and its palladium(II) and platinum(II) complexes are also described.
URI: http://dx.doi.org/10.1039/c1dt10459d
http://dspace.library.iitb.ac.in/jspui/handle/100/14287
ISSN: 1477-9226
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