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|Title: ||Palladium(II)-Catalyzed Direct Alkoxylation of Arenes: Evidence for Solvent-Assisted Concerted Metalation Deprotonation|
|Authors: ||ANAND, M|
|Keywords: ||C-H BOND|
|Issue Date: ||2011|
|Publisher: ||AMER CHEMICAL SOC|
|Citation: ||ORGANIC LETTERS,13(18)4802-4805|
|Abstract: ||Density functional theory investigations on the mechanism of palladium acetate catalyzed direct alkoxylation of N-methoxybenzamide in methanol reveal that the key steps involve solvent-assisted N-H as well as C-H bond activations. The transition state for the critical palladium-carbon bond formation through a concerted metalation deprotonation (CMD) process leading to a palladacycle intermediate has been found to be more stable in the methanol-assisted pathway as compared to an unassisted route.|
|Appears in Collections:||Article|
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