DSpace at IIT Bombay >
IITB Publications >
Please use this identifier to cite or link to this item:
|Title: ||Boron Complexes of Oxasmaragdyrin, a Core-Modified Expanded Porphyrin|
|Authors: ||RAO, MR|
|Keywords: ||ELECTROCHEMICAL PROPERTIES|
|Issue Date: ||2011|
|Publisher: ||AMER CHEMICAL SOC|
|Citation: ||JOURNAL OF ORGANIC CHEMISTRY,76(9)3582-3587|
|Abstract: ||We report the synthesis of first examples of BF(2) and B(OR)(2) complexes of oxasmaragdyrin, the expanded core-modified porphyrin, in decent yields under very simple reaction conditions at room temperature. The boron complexation of oxasmaragdyrin alters the electronic properties of the macrocycle significantly as evident by various spectroscopic techniques. Our preliminary studies indicated that the B(OH)(2)-smaragdyrin complex can act as a selective neutral fluoride ion sensor.|
|Appears in Collections:||Article|
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.