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|Title: ||Synthesis of Maradolipid|
|Authors: ||SARPE, VA|
|Keywords: ||ONE-POT PROTECTION|
|Issue Date: ||2011|
|Publisher: ||AMER CHEMICAL SOC|
|Citation: ||JOURNAL OF ORGANIC CHEMISTRY,76(16)6866-6870|
|Abstract: ||The first synthesis of maradolipid, a unique dissymmetrically 6,6'-di-O-acylated trehalose glycolipid isolated from C. elegans, is accomplished in five steps starting from trehalose in 45% overall yield. The short synthesis relies on dissymmetrization of trehalose core via regioselective acylation of a 2,3,4,2',3',4'-hexa-O-TMS trehalose 6,6'-diol derivative as a key step.|
|Appears in Collections:||Article|
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