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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/100/1387

Title: Field optimized initial state based control of photodissociation
Authors: VANDANA, K
BAIRAGI, DB
GROSS, P
MISHRA, MK
Keywords: selective vibrational-excitation
curve-crossing reactions
laser control
molecular-dynamics
quantum dynamics
bond breaking
systems
frequency
eigenvalues
chemistry
Issue Date: 1998
Publisher: INDIAN ACADEMY SCIENCES
Citation: PRAMANA-JOURNAL OF PHYSICS,50(6)521-534
Abstract: A new scheme for controlling photodissociation through preparation of a variationally optimized linear superposition of field free vibrational eigenstates is applied for selective control of IBr and HI dissociation. The dependence of photodissociation on various field parameters and initial conditions is examined to investigate the mechanistic basis of selective control. The parametric equations of motion approach for determining vibrational dynamics as a function of field parameters without having to solve the time dependent Schrodinger equation explicitly for each field parameter separately is outlined and its use to identify field characteristics which will provide the requisite population mix represented by the optimal linear superposition of vibrational states is advocated.
URI: http://dx.doi.org/10.1007/BF02846043
http://dspace.library.iitb.ac.in/xmlui/handle/10054/14564
http://hdl.handle.net/100/1387
ISSN: 0304-4289
Appears in Collections:Proceedings papers

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