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Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/jspui/handle/100/13867

Title: Boron Complexes of Oxasmaragdyrin, a Core-Modified Expanded Porphyrin
Authors: RAO, MR
RAVIKANTH, M
Keywords: ELECTROCHEMICAL PROPERTIES
CHEMISTRY
RECEPTORS
ANION
SMARAGDYRINS
SAPPHYRIN
BODIPY
LIGAND
DYES
Issue Date: 2011
Publisher: AMER CHEMICAL SOC
Citation: JOURNAL OF ORGANIC CHEMISTRY,76(9)3582-3587
Abstract: We report the synthesis of first examples of BF(2) and B(OR)(2) complexes of oxasmaragdyrin, the expanded core-modified porphyrin, in decent yields under very simple reaction conditions at room temperature. The boron complexation of oxasmaragdyrin alters the electronic properties of the macrocycle significantly as evident by various spectroscopic techniques. Our preliminary studies indicated that the B(OH)(2)-smaragdyrin complex can act as a selective neutral fluoride ion sensor.
URI: http://dx.doi.org/10.1021/jo200295b
http://dspace.library.iitb.ac.in/jspui/handle/100/13867
ISSN: 0022-3263
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