Cyclodimerization of phenyliodoacetylene with elemental tellurium: New pathway to 1.3-ditellurofulvenes

Abstract

Thermal reaction between PhC Cl and powdered Te afforded a mixture of (E)-4-iodo-2-(iodo(phenyl)-5-phenyl-1,3-ditellurofulvene (1) and (Z)-4-iodo-2-(iodo(phenyl)-5-phenyl-1-(diiodo),3-ditellurofulvene (2), which was subsequently reduced to (Z)-4-iodo-2-(iodo(pheny1)-5-phenyl-1,3-ditellurofulvene (3). Formation of 1 and 3 as the thermodynamically most stable products has been rationalized using density functional theory (DFT) calculations. Molecular structures of 1-3 were established crystallographically. In the solid state the coordination sphere of both tellurium atoms in 2 is extended by weak intermolecular Te center dot center dot center dot pi interactions with the solvate molecule of toluene which completes the pseudo-trigonal bipyramidal coordination geometry around each Te atom and assembles 2 into the chains along the crystallographic c-axis. (c) 2010 Elsevier B.V. All rights reserved.