Please use this identifier to cite or link to this item: http://dspace.library.iitb.ac.in/xmlui/handle/100/1286
Title: Oxo-metal complexes of alkoxo rich ligands and reactivity of vanadium complexes
Authors: RAO, CP
SREEDHARA, A
Keywords: Schiff-Bases
Bromoperoxidase
Monooxovanadium(V)
Salicylaldehyde
Spectroscopy
Derivatives
Oxidation
Acid
Issue Date: 1999
Publisher: INDIAN ACADEMY SCIENCES
Citation: PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES,111(3)479-487
Abstract: Ore-metal centers, such as, VO3+, cis-VO2+, cis-MoO22+ and trans-UO22+ exhibited different coordination geometries and charge types to result in totally nine different types of structures, all of which were characterized by single crystal X-ray diffraction. Aqueous stability, reactivity towards acid, H2O2 and bromide of vanadium complexes are studied using absorption and V-51 NMR spectra. Catalytic nature of the bromination reaction by vanadium complexes has also been addressed.
URI: http://dspace.library.iitb.ac.in/xmlui/handle/10054/14472
http://hdl.handle.net/100/1286
ISSN: 0253-4134
Appears in Collections:Proceedings papers

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