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|Title: ||Oxo-metal complexes of alkoxo rich ligands and reactivity of vanadium complexes|
|Authors: ||RAO, CP|
|Issue Date: ||1999|
|Publisher: ||INDIAN ACADEMY SCIENCES|
|Citation: ||PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES,111(3)479-487|
|Abstract: ||Ore-metal centers, such as, VO3+, cis-VO2+, cis-MoO22+ and trans-UO22+ exhibited different coordination geometries and charge types to result in totally nine different types of structures, all of which were characterized by single crystal X-ray diffraction. Aqueous stability, reactivity towards acid, H2O2 and bromide of vanadium complexes are studied using absorption and V-51 NMR spectra. Catalytic nature of the bromination reaction by vanadium complexes has also been addressed.|
|Appears in Collections:||Proceedings papers|
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